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A Facile Surface Passivation Enables Thermally Stable and Efficient Planar Perovskite Solar Cells Using a Novel IDTT-Based Small Molecule Additive

Title of paper
A Facile Surface Passivation Enables Thermally Stable and Efficient Planar Perovskite Solar Cells Using a Novel IDTT-Based Small Molecule Additive
Author
[박태호 교수 연구실]_IDTT 패시베이션을 통한 열안정 페로브스카이트 태양전지 개발
Publication in journal
Advanced Energy Materials 2021, 2003829
Publication date
20210311

 

[Abstract] 
Although perovskite solar cells (PSCs) have attracted enormous attention owing to their fascinating optoelectronic properties and solution processability, defects in PSCs, which adversely affect efficiency and stability, are still not completely resolved. Herein, a novel indacenodithieno[3,2‐b]thiophene‐based small molecule (SM) additive (IDTT‐ThCz), capable of interacting with perovskite layers, is developed. In particular, the IDTT‐ThCz, which can perform a surface passivation, is introduced into the perovskite layer to significantly suppress perovskite defects via antisolvent treatment. Furthermore, this facile surface passivation not only significantly improves the charge extraction capability, but also prevents perovskite degradation. The IDTT‐ThCz‐treated PSCs exhibits a power conversion efficiency (PCE) of 22.5% and retains 95% of its initial PCE after 500 h storage under thermal condition (85 °C), representing the most remarkable efficiency as well as stability among the SM additives reported to date.

 

DOI: 10.1002/aenm.202003829 

Link: https://doi.org/10.1002/aenm.202003829