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Donor–Acceptor Type Dopant-Free, Polymeric Hole Transport Material for…

Year of publication
Title of paper
Donor–Acceptor Type Dopant-Free, Polymeric Hole Transport Material for Planar Perovskite Solar Cells (19.8%)
Author
[박태호교수 연구실]
Publication in journal
Advanced Energy Materials 2017,
Publication date
20170922
[Abstract]
Organic–inorganic hybrid perovskite has led to the development of new solar cells with outstanding efficiency. In perovskite solar cells (PSCs), perovskite is sandwiched between a working electrode (fluorine-doped tin oxide) and a counter electrode (gold, Au). In order to transport charges and block opposite charges, charge transport layers are inserted between perovskite and the electrodes. In particular, a hole transport layer is important because it generally prevents perovskite from exposure to air. Therefore, it is necessary to investigate dopant-free and hydrophobic polymeric hole transport materials (HTMs). In this study, a novel polymeric HTM (PTEG) is synthesized by controlling the solubility using a tetraethylene glycol group. The planar-PSC employing PTEG exhibits an efficiency of 19.8% without any dopants, which corresponds to the highest value reported to date. This study offers a fundamental strategy for designing and synthesizing various polymeric HTMs.
 
DOI: 10.1002/aenm.201701935