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Gradated Mixed Hole Transport Layer in Perovskite Solar Cell: Improving Moisture Stability and Efficiency
Title of paper Gradated Mixed Hole Transport Layer in Perovskite Solar Cell: Improving Moisture Stability and Efficiency
Author [박태호교수 연구실]
Publication in journal ACS Applied Matererial and Interfaces 2017, 9 (33), 27720–27726
Publication date 2017-08-01

 
[abstract]
We demonstrate a simple and facile way to improve the efficiency and moisture stability of perovskite solar cells using commercially available hole transport materials, 2,2,7,7-tetrakis-(N,N-di-4-methoxyphenylamino)-9,9-spirobifluorene (spiro-OMeTAD) and poly(3-hexylthiophene) (P3HT). The hole transport layer (HTL) composed of mixed spiro-OMeTAD and P3HT exhibited favorable vertical phase separation. The hydrophobic P3HT was more distributed near the surface (the air atmosphere), whereas the hydrophilic spiro-OMeTAD was more distributed near the perovskite layer. This vertical separation resulted in improved moisture stability by effectively blocking moisture in air. In addition, the optimized composition of spiro-OMeTAD and P3HT improved the efficiency of the solar cells by enabling fast intramolecular charge transport. In addition, a suitable energy level alignment facilitated charge transfer. A device fabricated using the mixed HTL exhibited enhanced performance, demonstrating 18.9% power conversion efficiency and improved moisture stability.
 
DOI: 10.1021/acsami.7b07071